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a, \(CuO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Cu+H_2O\)
b, \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
Theo PT: \(n_{CH_3COOH}=2n_{CuO}=0,2\left(mol\right)\Rightarrow C_{M_{CH_3COOH}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
c, \(n_{\left(CH_3COO\right)_2Cu}=n_{Cu}=0,1\left(mol\right)\Rightarrow m_{\left(CH_3COO\right)_2Cu}=0,1.182=18,2\left(g\right)\)
`n_{Na_2O}={4,6}/{62}\approx 0,074(mol)`
`Na_2O+H_2O->2NaOH`
`0,074->0,074->0,148(mol)`
`a)\ C_{M\ NaOH}={0,148}/{0,2}=0,74M`
`b)\ C\%_{NaOH}={0,148.40}/{200.1,12}.100\%\approx 2,64\%`
\(n_{CuSO4}=\dfrac{16\%.50}{100\%.160}=0,05\left(mol\right)\)
Pt : \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
0,05-------->0,1---------->0,05--------->0,05
a) \(C\%_{ddNaOH}=\dfrac{0,1.40}{250}.100\%=1,6\%\)
b) \(m_{ddspu}=50+250-0,05.98=295,1\left(g\right)\)
\(C\%_{Na2SO4}=\dfrac{0,05.142}{295,1}.100\%=2,41\%\)
\(n_{CuSO_4}=\dfrac{m_{dd}\cdot C\%}{100\cdot M}=\dfrac{50\cdot16\%}{100\cdot\left(64+32+16\cdot4\right)}=0,05\left(mol\right)\)
\(PTHH:CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
1 2 1 1
0,05 0,1 0,05 0,05 (mol)
\(a)C\%_{NaOH}=\dfrac{n\cdot100\cdot M}{m_{dd}}=\dfrac{01\cdot100\cdot\left(23+16+1\right)}{250}=1,6\%\)
\(b)m_{dd-sau-pư}=m_{dd_đ}+m_{ct_đ}-m\downarrow-m\uparrow\)
\(=50+250-\left(0,05\cdot23+32+16\cdot4\right)=294,05\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{n\cdot100\cdot M}{m_{dd}}=\dfrac{0,05\cdot100\cdot\left(23\cdot2+32+16\cdot4\right)}{294,05}\approx2,41\%.\)
Bài 1
\(a,n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\\ CuO+2HCl\xrightarrow[]{}CuCl_2+H_2O\\ n_{CuCl_2}=n_{CuO}=0,2mol\\ m_{CuCl_2}=0,2.135=27\left(g\right)\\ b.n_{HCl}=0,2.2=0,4\left(mol\right)\\ C_{MHCl}=\dfrac{0,4}{0,5}=0,8\left(M\right)\)
Bài 5
\(a,n_{NaOH}=0,2.1=0,2\left(mol\right)\\ 2NaOH+H_2SO_4\xrightarrow[]{}Na_2SO_4+2H_2O\\ n_{H_2SO_4}=0,2:2=0,1\left(mol\right)\\ C_{MH_2SO_4}=\dfrac{0,1}{0,4}=0,25\left(M\right)\\ b,n_{Na_2SO_4}=0,2:2=0,1\left(mol\right)\\ C_{MNa_2SO_4}=\dfrac{0,1}{0,2+0,4}=\dfrac{1}{6}\left(M\right)\\ c,m_{Na_2SO_4}=0,1.142=14,2\left(g\right)\)
Ta có: \(n_{NaOH}=0,1.0,5=0,05\left(mol\right)\)
PT: \(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)
Theo PT: \(n_{CH_3COOH}=n_{CH_3COONa}=n_{NaOH}=0,05\left(mol\right)\)
a, \(C_{M_{CH_3COOH}}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)
b, \(m_{CH_3COONa}=0,05.82=4,1\left(g\right)\)
a)
$K_2SO_4 + BaCl_2 \to BaSO_4 + 2KCl$
b)
$n_{K_2SO_4} = 0,2.2 = 0,4(mol)$
$n_{BaCl_2} = 0,3.1 = 0,3(mol)$
Ta thấy :
$n_{K_2SO_4} : 1 > n_{BaCl_2} : 1$ nên $K_2SO_4$ dư
$n_{BaSO_4} = n_{BaCl_2} = 0,3(mol)$
$m_{BaSO_4} = 0,3.233 = 69,9(gam)$
c) $n_{K_2SO_4} = 0,4 - 0,3 = 0,1(mol)$
$V_{dd\ sau\ pư} = 0,2 + 0,3 = 0,5(lít)$
$C_{M_{K_2SO_4} } = \dfrac{0,1}{0,5} = 0,2M$
$C_{M_{KCl}} = \dfrac{0,6}{0,5} = 1,2M$
\(3NaOH+FeCl_3\rightarrow Fe\left(OH\right)_3+3NaCl\)
\(n_{NaCl}=n_{NaOH}=0,2.3=0,6\left(mol\right)\)
=> \(C_{M\left(NaCl\right)}=\dfrac{0,6}{0,2}=3M\)
\(n_{Fe\left(ỌH\right)_3}=\dfrac{1}{3}n_{NaOH}=0,2\left(mol\right)\)
\(2Fe\left(OH\right)_3-^{t^o}\rightarrow Fe_2O_3+3H_2O\)
Ta có \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,1\left(mol\right)\)
=> m Fe2O3 = 0,1 . 160=16(g)
\(n_{MgCl_2}=0,15.0,2=0,03(mol)\\ PTHH:MgCl_2+2NaOH\to Mg(OH)_2\downarrow +2NaCl\\ a,n_{Mg(OH)_2}=n_{MgCl_2}=0,03(mol)\\ \Rightarrow m_{\downarrow}=m_{Mg(OH)_2}=0,03.58=1,74(g)\\ b,n_{NaOH}=2n_{MgCl_2}=0,06(mol)\\ \Rightarrow C_{M_{NaOH}}=\dfrac{0,06}{0,3}=0,2M\\ c,PTHH:Mg(OH)_2\xrightarrow{t^o}MgO+H_2O\\ \Rightarrow n_{MgO}=n_{Mg(OH)_2}=0,03(mol)\\ \Rightarrow m_{A}=m_{MgO}=0,03.40=1,2(g)\)
sao đề lạ vậy