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Gọi số mol KClO3, KMnO4 trong mỗi phần là a, b (mol)
Phần 1:
\(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
mY = 122,5a + 158b - 0,1.32 = 122,5a + 158b - 3,2 (g)
Bảo toàn O: \(n_{O\left(Y\right)}=3a+4b-0,2\left(mol\right)\)
\(\%O=\dfrac{16\left(3a+4b-0,2\right)}{122,5a+158b-3,2}.100\%=34,5\%\)
=> 5,7375a + 9,49b = 2,096 (1)
Phần 2:
PTHH: 2KClO3 --to--> 2KCl + 3O2
a----------->a
2KMnO4 --to--> K2MnO4 + MnO2 + O2
b------------>0,5b------>0,5b
=> 74,5a + 142b = 29,1 (2)
(1)(2) => a = 0,2 (mol); b = 0,1 (mol)
=> \(\left\{{}\begin{matrix}\%m_{KClO_3}=\dfrac{0,2.122,5}{0,2.122,5+0,1.158}.100\%=60,8\%\\\%m_{KMnO_4}=\dfrac{0,1.158}{0,2.122,5+0,1.158}.100\%=39,2\%\end{matrix}\right.\)
\(a,PTHH:2KMnO_4\rightarrow^{t^o}K_2MnO_4+MnO_2+O_2\\ b,n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ \Rightarrow m_{O_2}=0,3\cdot32=9,6\left(g\right)\\ \Rightarrow m_{KMnO_4\left(bđ\right)}=m_{\text{chất rắn}}+m_{O_2}=109,6\left(g\right)\\ c,n_{MnO_2}=0,3\left(mol\right)\\ \Rightarrow m_{MnO_2}=0,3\cdot87=26,1\left(g\right)\\ \Rightarrow\%_{MnO_2}=\dfrac{26,1}{100}\cdot100\%=26,1\%\\ \Rightarrow\%_{KMnO_4}=100\%-26,1\%=73,9\%\)
1) \(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
mA = mKMnO4(bđ) - mO2 = 79 - 0,15.32 = 74,2 (g)
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
0,3<-----------0,15<----0,15<---0,15
=> \(H=\dfrac{0,3.158}{79}.100\%=60\%\)
2)
\(\left\{{}\begin{matrix}\%m_{K_2MnO_4}=\dfrac{0,15.197}{74,2}.100\%=39,825\%\\\%m_{MnO_2}=\dfrac{0,15.87}{74,2}.100\%=17,588\%\\\%m_{KMnO_4\left(không.pư\right)}=\dfrac{79-0,3.158}{74,2}.100\%=42,587\%\end{matrix}\right.\)
3) \(n_{KMnO_4\left(không.pư\right)}=\dfrac{79}{158}-0,3=0,2\left(mol\right)\)
PTHH: 2KMnO4 + 16HCl --> 2KCl + 2MnCl2 + 5Cl2 + 8H2O
0,2----------------------------------->0,5
K2MnO4 + 8HCl --> 2KCl + MnCl2 + 2Cl2 + 4H2O
0,15-------------------------------->0,3
MnO2 + 4Hcl --> MnCl2 + Cl2 + 2H2O
0,15------------------->0,15
=> \(V_{Cl_2}=22,4\left(0,5+0,3+0,15\right)=21,28\left(l\right)\)
\(n_{KMnO_4}=\dfrac{79}{158}=0,5mol\)
\(n_{O_2}=\dfrac{3,36}{22,4}=0,15mol\)
\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,5 0,15
a)\(m_{KMnO_4}=0,15\cdot197=29,55g\)
\(m_{MnO_2}=0,15\cdot87=13,05g\)
\(m_{CRắn}=m_{KMnO_4}+m_{MnO_2}=29,55+13,05=42,6g\)
\(n_{KMnO_4pư}=0,15\cdot2=0,3mol\)
\(H=\dfrac{0,3}{0,5}\cdot100\%=60\%\)
b)\(m_{O_2}=0,15\cdot32=4,8g\)
\(\%m_{K_2MnO_4}=\dfrac{29,55}{42,6}\cdot100\%=69,37\%\)
\(\%m_{MnO_2}=100\%-69,37\%=30,63\%\)
a) \(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
b) Đặt x là số mol của \(KMnO_4\)
\(\Rightarrow n_{K_2MnO_4}=\frac{1}{2}n_{KMnO_4}=\frac{1}{2}x\)
Ta có : \(m_{KMnO_4}-m_{K_2MnO_4}=2,4\left(g\right)\)
\(\Leftrightarrow158x-\frac{197}{2}x=2,4\)
\(\Leftrightarrow x\approx0,04\left(mol\right)\)
\(\Rightarrow m_{KMnO_4}=0,04\times158=6,32\left(g\right)\)
Gọi n KMnO4 = a
n KClO3 = b ( mol )
--> 158a + 122,5 b = 43,3
PTHH :
\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\uparrow\)
0,9b 1,35b
\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,9a 0,45a
\(\%Mn=\dfrac{55a}{43,3-32\left(0,45a+1,35b\right)}=24,103\%\)
\(\rightarrow a=0,15\)
\(b=0,16\)
\(m_{KMnO_4}=0,15.158=23,7\left(g\right)\)
\(m_{KClO_3}=0,16.122,5=19,6\left(g\right)\)