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\(n_{Br_2}=\dfrac{4}{160}=0,025mol\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,025 0,025 ( mol )
\(V_{hh}=\dfrac{2,8}{22,4}=0,125mol\)
\(\%V_{C_2H_4}=\dfrac{0,025}{0,125}.100=20\%\)
\(\%V_{CH_4}=100\%-20\%=80\%\)
a) \(n_{Br_2\left(p\text{ư}\right)}=\dfrac{6,4}{160}=0,04\left(mol\right);n_{hh}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,04<--0,04
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,04}{0,6}.100\%=6,67\%\\\%V_{CH_4}=100\%-6,67\%=93,33\%\end{matrix}\right.\)
b) \(n_{CH_4}=0,6-0,04=0,56\left(mol\right)\)
PTHH: \(CH_4+2O_2\xrightarrow[]{t^o}CO_2+2H_2O\)
0,56----------->0,56
\(C_2H_4+3O_2\xrightarrow[]{t^o}2CO_2+2H_2O\)
0,04----------->0,08
\(\Rightarrow V_{CO_2}=\left(0,08+0,56\right).22,4=14,336\left(l\right)\)
\(n_{hh}=\dfrac{3,36}{22,4}=0,15mol\)
\(n_{Br_2}=\dfrac{2,4}{160}=0,015mol\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
0,0075 0,015 ( mol )
\(V_{C_2H_2}=0,0075.22,4=0,168l\)
\(V_{CH_4}=3,36-0,168=3,192l\)
\(\%V_{C_2H_2}=\dfrac{0,168}{3,36}.100=5\%\)
\(\%V_{CH_4}=100\%-5\%=95\%\)
PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Gọi: \(\left\{{}\begin{matrix}n_{C_2H_4}=x\left(mol\right)\\n_{C_2H_2}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow x+y=\dfrac{2,24}{22,4}=0,1\left(mol\right)\left(1\right)\)
\(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=x+2y=\dfrac{24}{160}=0,15\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow x=y=0,05\left(mol\right)\)
\(\Rightarrow\%V_{C_2H_4}=\%V_{C_2H_2}=\dfrac{0,05.22,4}{2,24}.100\%=50\%\)
\(n_{hh}=6,72:22,4=0,3mol\\ C_2H_2+2Br_2->C_2H_2Br_4\\ C_2H_4+Br_2->C_2H_2Br_2\\ n_{Br_2}=0,4mol\\ n_{C_2H_2}=a;n_{C_2H_4}=b\\ a+b=0,3\\ 2a+b=0,4\\ a=0,2;b=0,1\\ \%V_{C_2H_2}=\dfrac{0,2}{0,3}.100\%=66,67\%\\ \%V_{C_2H_4}=33,33\%\)
1/2 hỗn hợp có 0,1 mol C2H2 và 0,05mol C2H4
\(BT.C:n_{CO_2}=2n_{C_2H_2}+2n_{C_2H_4}=0,3mol\\ n_{CaCO_3}=n_{CO_2}=0,3\\ m_{KT}=0,3.100=30g\)
nBr2 = 32/160 = 0,2 (mol)
PTHH: C2H4 + Br2 -> C2H4Br2
Mol: 0,2 <--- 0,2
VC2H4 = 0,2 . 22,4 = 4,48 (l)
%VC2H4 = 4,48/6,2 = 72,25%
%VCH4 = 100% - 72,25% = 27,75%
a) \(n_{Br_2}=\dfrac{32}{160}=0,2\left(mol\right)\)
PTHH: C2H2 + 2Br2 --> C2H2Br4
0,1<-----0,2
=> mC2H2 = 0,1.26 =2,6 (g)
\(\%m_{C_2H_2}=\dfrac{2,6}{8}.100\%=32,5\%\)
\(\%m_{CH_4}=\dfrac{8-2,6}{8}.100\%=67,5\%\)
b) \(n_{CH_4}=\dfrac{8-2,6}{16}=0,3375\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,3375->0,675
2C2H2 + 5O2 --to--> 4CO2 + 2H2O
0,1---->0,25
=> VO2 = (0,675 + 0,25).22,4 = 20,72 (l)
=> Vkk = 20,72.5 = 103,6 (l)
refer
Gọi x, y lần lượt là số mol của C2H4, C2H2 ( x, y > 0 )
nBr2 = 0,2 mol
C2H4 + Br2 → C2H4Br2
x............x...............x
C2H2 + 2Br2 → C2H2Br4
y.............2y..............y
Ta có hệ
{28x+26y=4,1x+2y=0,2{28x+26y=4,1x+2y=0,2
⇒ {x=0,1y=0,05{x=0,1y=0,05
⇒ %C2H4 = 0,1.28.100%4,10,1.28.100%4,1≈≈68,3%
⇒ %C2H2 = 0,05.26.100%4,10,05.26.100%4,1 ≈≈ 31,7%
C2H4 + 3O2 ---to---> 2CO2 + 2H2O
0,1.........0,3
⇒ VO2 = 0,3.22,4 = 6,72 (l)
2C2H2 + 5O2 ---to---> 4CO2 + 2H2O
0,05.......0,125
⇒ VO2 = 0,125.22,4 = 2,8 (l)
⇒ ∑∑VO2 = 6,72 + 2,8 = 9,52 (l)